Posted by Toledo Bear Mace works well
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I never would pepper spray/mace a dog, and I've dealt with vicious ones.
It's inhumane to have an animal rubbing its eyes in gravel to try to stop the pain.
Humans can burn through the pain... and then they will really be pissed.
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If the wind blows it in your face or the perp barrels into you after being sprayed you better have practice with it beforehand.
What goes around... goes around